Abstract
Tezisda akrolein, krotonaldegid, metakrolein va sinnamik aldegid kabi to'yinmagan aldegidlarning atsetilen bilan etinillanishi orqali ikkilamchi atsetilen (propargil) spirtlariga aylanishi ko'rib chiqilgan. Mis va kumush asosidagi nanozarrachali katalizatorlarning roli, reaksiya mexanizmi hamda 1,2-qo'shilish selektivligiga ta'sir etuvchi omillar tahlil qilingan. Hosil bo'ladigan spirtlarning spektral tavsiflari, fizik-kimyoviy xossalari va kimyoviy o'zgarishlari bayon etilgan.
References
1. Reppe W. Chemie und Technik der Acetylen-Druck-Reaktionen. Weinheim: Verlag Chemie, 1951.
2. Trotuş I.-T., Zimmermann T., Schüth F. Catalytic reactions of acetylene: a feedstock for the chemical industry revisited // Chem. Rev. 2014. Vol. 114, No. 3. P. 1761–1782.
3. Astruc D., Lu F., Aranzaes J.R. Nanoparticles as recyclable catalysts: the frontier between homogeneous and heterogeneous catalysis // Angew. Chem. Int. Ed. 2005. Vol. 44. P. 7852–7872.
4. Frantz D.E., Fässler R., Carreira E.M. Facile enantioselective synthesis of propargylic alcohols by direct addition of terminal alkynes to aldehydes // J. Am. Chem. Soc. 2000. Vol. 122. P. 1806–1807.
5. Anand N.K., Carreira E.M. A simple, mild, catalytic, enantioselective addition of terminal acetylenes to aldehydes // J. Am. Chem. Soc. 2001. Vol. 123. P. 9687–9688.
6. Trost B.M., Weiss A.H. The enantioselective addition of alkyne nucleophiles to carbonyl groups: a direct route to optically active propargylic alcohols // Adv. Synth. Catal. 2009. Vol. 351. P. 963–983.
7. Swaminathan S., Narayanan K.V. The Rupe and Meyer–Schuster rearrangements // Chem. Rev. 1971. Vol. 71. P. 429–438.
8. Lindlar H. Ein neuer Katalysator für selektive Hydrierungen // Helv. Chim. Acta. 1952. Vol. 35. P. 446–450.
9. Sheldon R.A. The E factor: fifteen years on // Green Chem. 2007. Vol. 9. P. 1273–1283.
10. Silverstein R.M., Webster F.X., Kiemle D.J. Spectrometric identification of organic compounds. 7th ed. New York: Wiley, 2005.
11. Astruc D. (ed.) Nanoparticles and catalysis. Weinheim: Wiley-VCH, 2008.